Okay...this thread has been cleaned up and reset for discussion. I know from a brief search online that there are many people who feel, have felt, or potentially will feel, predisposed to believing that dark roast coffee has more caffeine that light roast coffee & many others who believe the opposite. The first attempt to carry on a conversation regarding this went down in flames, but I'd like to know if anyone here knows of any really good studies on this issue.
I have my opinion, because the arguments appeal to me. I am looking for a more conclusive basis for my belief, and in the face of overwhelming evidence, will become an advocate of the truth!
What I do know is that running experiments to extract caffeine from R&G coffee would involve, most effectively, dichloromethane, and that is some toxic stuff. This should be done with plenty of ventilation with a blower fan sucking air away from the extraction equipment as from a fume hood.
Another consideration is acknowledging the need for taking the identical mass of green coffee and putting it through the roasting process, and sampling the resulting caffeine content at various degrees of roast. Complications arise from failure to account for the reduction in bean density because of moisture loss. If you grind up the coffee and THEN measure out a weight for light roast and an identical weight for dark roast, your samples are not same because it took more of the dark roasted beans to equal the weight of the light roasted beans. The best experiment would take green beans of uniform size and density. Doing so will provide the best data and is worth the effort. On the back end, the difference in weight due to moisture loss must be accounted for in the samples weighed out for extraction. Other considerations are probably of less effect on the results, in my opinion. So it is my hope to find that elusive data that settles this once and for all....