In response to the OP, I'd say that a food chemist could be needed to supply a good answer outside of a layman's opinion. But, from my reading - yes - reactions can take place at boiling temperature (or even a little lower) - that cause existing compounds in the coffee to morph into something else. High fructose corn syrup is an example of a substance (some say) you should never boil (in other words, never use soda to sweeten your coffee). With so many compounds in a cup of joe, I'd say that even the chemist will have trouble with this one.
Then again, I'm the newbie who still takes instant once in awhile. After reading the posts on this forum, though, I think I'm going to quit that completely. It sounds like the stuff is dangerous. But hey - at least I've not been using Folgers. Cafe Bustelo seems to be taking more and more shelf space around here.
I've tried using the organic beans in the grocery, but found that they must sit on the shelf too long, because the coffee always tastes stale. So - that'd be a reason to buy from a local roaster I suppose. Forgive all my newbieness here. I wonder how much local roasters use organic beans? Is it a majority?