This report isn't all about flavored coffees - it has to do with the roasting and grinding process in regular coffee.
Air sampling during specific tasks, such as roasting, grinding, opening storage bins or containers with roasted coffee beans, and pouring and adding flavorings, is important. For example, at a coffee processing facility, a 15-minute air sample collected at a small open hatch in the lid of a grinding/packaging room mezzanine hopper holding unflavored ground coffee above an active packaging line measured concentrations of 14,300 ppb diacetyl and 18,400 ppb 2,3-pentanedione; workers opened these hatches momentarily to monitor coffee levels in the hoppers (Bailey et al. 2015)
Diacetyl and 2,3-pentanedione are also naturally produced and released during the coffee roasting process (Daglia et al. 2007). Grinding roasted coffee beans produces greater surface area for the off-gassing of these and other chemicals (Akiyama et al. 2003).